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期刊论文 45

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Rapid method for on-site determination of phenolic contaminants in water using a disposable biosensor

Yuanting LI, Dawei LI, Wei SONG, Meng LI, Jie ZOU, Yitao LONG

《环境科学与工程前沿(英文)》 2012年 第6卷 第6期   页码 831-838 doi: 10.1007/s11783-012-0393-z

摘要: A disposable biosensor was fabricated using single-walled carbon nanotubes, gold nanoparticles and tyrosinase (SWCNTs-AuNPs-Tyr) modified screen-printed electrodes. The prepared biosensor was applied to the rapid determination of phenolic contaminants within 15 minutes. The SWCNTs-AuNPs-Tyr bionanocomposite sensing layer was characterized with scanning electron microscopy, electrochemical impedance spectroscopy and cyclic voltammetry methods. The characterization results revealed that SWCNTs could lead to a high loading of tyrosinase (Tyr) with the large surface area and the porous morphology, while AuNPs could retain the bioactivity of Tyr and enhance the sensitivity. The detection conditions, including working potential, pH of supporting electrolyte and the amount of Tyr were optimumed. As an example, the biosensor for catechol determination displayed a linear range of 8.0 × 10 to 2.0 × 10 mol·L with a detection limit of 4.5 × 10 mol·L (S/ = 3). This method has a rapid response time within 10 s, and shows excellent repeatability and stability. Moreover, the resulting biosensor could be disposable, low-cost, reliable and easy to carry. This kind of new Tyr biosensor provides great potential for rapid, on-site and cost-effective analysis of phenolic contaminants in environmental water samples.

关键词: on-site determination     tyrosinase biosensor     phenolic contaminants     single-walled carbon nanotubes     gold nanoparticles     screen-printed electrodes    

Defect passivation on cast-mono crystalline screen-printed cells

Alison WENHAM,Lihui SONG,Malcolm ABBOTT,Iskra ZAFIROVSKA,Sisi WANG,Brett HALLAM,Catherine CHAN,Allen BARNETT,Stuart WENHAM

《能源前沿(英文)》 2017年 第11卷 第1期   页码 60-66 doi: 10.1007/s11708-016-0443-5

摘要: Cast-mono crystalline silicon wafers contain crystallographic defects, which can severely impact the electrical performance of solar cells. This paper demonstrates that applying hydrogenation processes at moderate temperatures to finished screen print cells can passivate dislocation clusters within the cast-mono crystalline silicon wafers far better than the hydrogenation received during standard commercial firing conditions. Efficiency enhancements of up to 2% absolute are demonstrated on wafers with high dislocation densities. The impact of illumination to manipulate the charge state of hydrogen during annealing is investigated and found to not be significant on the wafers used in this study. This finding is contrary to a previous study on similar wafers that concluded increased H or H from laser illumination was responsible for the further passivation of positively charged dangling bonds within the dislocation clusters.

关键词: silicon solar cell     dislocation     cast-mono     laser     hydrogen passivation    

Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

《能源前沿(英文)》 2017年 第11卷 第1期   页码 72-77 doi: 10.1007/s11708-016-0428-4

摘要: The improvement of adhesion strength and durability of plated contacts is required for cell manufacturers to gain confidence for large-scale manufacturing. To overcome weak adhesion at the metal/Si interface, new approaches were developed. These involve the formation of laser-ablated anchor points, or grooves in the extreme case of overlapping anchor points, in the heavily doped silicon surface. When plated, these features greatly strengthen the mechanical adhesion strength of the metal. A stylus-based adhesion tester was developed specifically for evaluating the effectiveness of plated contacts to smooth silicon surfaces. The use of such a tester was also extended in this work to textured and roughened surfaces to allow evaluation of different metal contacting approaches. The adhesion strengths for various metal contacting schemes were evaluated, including screen-printed silver contacts, nickel/copper (Ni/Cu) light-induced plated (LIP) contacts for laser-doped selective emitter (LDSE) cells, buried-contact solar cells (BCSCs), and Ni/Cu LIP contacts formed with laser-ablated anchoring points in selective emitter (LAASE) cells. The latter has superior adhesion strength. The standard “peel test” of the industry was compared to the stylus-based adhesion testing, with the latter shown value for testing metal contacts on smooth surfaces but with caution needed for use with textured or roughened surfaces.

关键词: light-induced plating     metal adhesion strength     copper plating     metal contacts     solar cell durability     silicon solar cells    

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

《环境科学与工程前沿(英文)》 2014年 第8卷 第6期   页码 945-951 doi: 10.1007/s11783-013-0615-z

摘要: A potentiometric cobalt-based screen-printing sensor was fabricated by electroplating cobalt on the surface of a screen-printing electrode as the sensitive layer for the determination of dihydrogenphosphate ( ) in wastewater samples. The electrochemical performance of this sensor was fully examined to determine its detection calibration, detection limit, response time, selectivity, and interference with pH, various ions, and dissolved oxygen (DO). The cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10 mol·L to 10 mol·L , yielding a detection limit of 3.16 × 10 mol?L and a slope of -37.51 mV?decade in an acidic solution (pH 4.0) of . DO and pH were found to interfere with sensor responses to phosphate. Ultimately, the performance of the sensor was validated for detecting wastewater samples from the Xiaojiahe Wastewater Treatment Plant against the standard spectrophotometric methods for analysis. The discrepancy between the two methods was generally ±5% (relative standard deviation). Aside from its high selectivity, sensitivity, and stability, which are comparable with conventional bulk Co-wire sensors, the proposed phosphate sensor presents many other advantages, such as low price, compactness, ease of use, and the possibility of integration with other analytical devices, such as flow injectors.

关键词: phosphate     cobalt     screen-printing technology     electroplate     wastewater    

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

《化学科学与工程前沿(英文)》 2023年 第17卷 第8期   页码 1010-1027 doi: 10.1007/s11705-023-2307-y

摘要: Powering the future, while maintaining strong socioeconomic growth and a cleaner environment, is going to be one of the biggest challenges faced by mankind nowadays. Thus, there is a transition from the use of fossil fuels to renewable energy sources. Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuring exciting properties: low-cost, hierarchical fibrous structures, hydrophilicity, biocompatible, mechanical flexibility, and renewability, which make it perfect for use in paper-based sustainable energy storage devices. This review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field. Recent advances and approaches to construct high mass loading paper electrodes toward high energy density batteries are evaluated and the limitations of paper-based cathodes are discussed. This will stimulate the use of natural resources and thereby the development of renewable electric energy systems based on sustainable technologies with low environmental impacts and carbon footprints.

关键词: cellulose     paper electrodes     Li-ion batteries     high energy density    

Cutting performance of surgical electrodes by constructing bionic microstriped structures

《机械工程前沿(英文)》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0728-9

摘要: Surgical electrodes rely on thermal effect of high-frequency current and are a widely used medical tool for cutting and coagulating biological tissue. However, tissue adhesion on the electrode surface and thermal injury to adjacent tissue are serious problems in surgery that can affect cutting performance. A bionic microstriped structure mimicking a banana leaf was constructed on the electrode via nanosecond laser surface texturing, followed by silanization treatment, to enhance lyophobicity. The effect of initial, simple grid-textured, and bionic electrodes with different wettabilities on tissue adhesion and thermal injury were investigated using horizontal and vertical cutting modes. Results showed that the bionic electrode with high lyophobicity can effectively reduce tissue adhesion mass and thermal injury depth/area compared with the initial electrode. The formation mechanism of adhered tissue was discussed in terms of morphological features, and the potential mechanism for antiadhesion and heat dissipation of the bionic electrode was revealed. Furthermore, we evaluated the influence of groove depth on tissue adhesion and thermal injury and then verified the antiadhesion stability of the bionic electrode. This study demonstrates a promising approach for improving the cutting performance of surgical electrodes.

关键词: surgical electrodes     tissue adhesion     thermal injury     bionic structures     cutting performance     medical tools    

An investigation on patient dose in screen-film diagnostic radiology in Lhasa City, Xizang Autonomous

null

《医学前沿(英文)》 2013年 第7卷 第4期   页码 506-509 doi: 10.1007/s11684-013-0294-y

摘要:

This study aimed to investigate patient dose in diagnostic screen-film radiographic examinations in the city of Lhasa, China. Seven out of the twenty-six hospitals registered with the Lhasa Health Bureau were included in the investigation. The entrance surface air Kerma (ESAK) of seven conventional screen-film radiology X-ray equipment in these hospitals was measured with a QA dosimeter in September 2012. The X-ray examinations were divided into three categories: PA (posterior-anterior) chest, upper/lower limb, and AP (anterior-posterior) lumbar spine. For each category, ESAKs were calculated and analyzed. The mean ESAK was 0.6 mGy for PA chest, 0.3 mGy for upper/lower limb, and 1.8 mGy for AP lumbar spine. In addition, the mean ESAK value recorded for PA chest X-ray examinations exceeded the corresponding value recommended by the International Atomic Energy Agency (0.4 mGy).

关键词: radiation dosage     radiology     radiation protection     radiography/statistics & numerical data    

Hollow-fiber gas penetration electrodes efficiently produce renewable synthetic fuels

《能源前沿(英文)》 2022年 第16卷 第5期   页码 700-705 doi: 10.1007/s11708-022-0842-8

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

《环境科学与工程前沿(英文)》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1581-0

摘要:

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis.

关键词: Waste printed circuit board     Catalyst     Pyrolysis     Kinetics    

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

《环境科学与工程前沿(英文)》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1723-z

摘要:

● Au, Ag and Pd were recovered from WPCBs with high efficiencies.

关键词: Thiosulfate     Printed circuit boards     Precious metals     Leaching     Hydrometallurgy    

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

《环境科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 167-174 doi: 10.1007/s11783-011-0308-4

摘要: Mechanical waste-processing methods, which combine crushing and separation processes for the recovery of valuable materials, have been widely applied in waste printed wiring board (PWB) treatment. However, both the high impact toughness and the tensile and flexural strengths of whole PWB with a laminated structure result in great energy consumption and severe abrasion of the cutters during multi-level crushing. In addition, the high temperatures occurring in continual crushing probably cause the decomposition of the polymer matrix. A thermal-crack method using residual steam as the heating medium has been developed to pre-treat waste PWBs. This treatment reduces the mechanical strength in order to improve the recovery rate of valuable materials in subsequent mechanical recycling. The changes of the PWBs’ macro-mechanical properties were studied to evaluate thermal expansion impacts associated with changes in temperature, and the dynamic dislocation micro-structures were observed to identify the fracture mechanism. The results showed that thermal cracking with steam at the temperature of 500 K can effectively attenuate the mechanical properties of waste PWBs, by reducing the impact, tensile and flexural strengths respectively, by 59.2%, 49.3% and 51.4%, compared to untreated PWB. Thermal expansion can also facilitate the separation of copper from glass fiber by reducing peel resistance by 95.4% at 500 K. It was revealed that the flexural fracture was a transverse cracking caused by concentrated stress when the heating temperature was less than 500 K, and shifted to a vertical cracking after exceeding 500 K.

关键词: waste printed wiring board (PWB)     residue steam     thermal-crack     mechanical properties    

Copper recovery from waste printed circuit boards concentrated metal scraps by electrolysis

Xiaonan Liu, Qiuxia Tan, Yungui Li, Zhonghui Xu, Mengjun Chen

《环境科学与工程前沿(英文)》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0997-4

摘要: Copper recovery is the core of waste printed circuit boards (WPCBs) treatment. In this study, we proposed a feasible and efficient way to recover copper from WPCBs concentrated metal scraps by direct electrolysis and factors that affect copper recovery rate and purity, mainly CuSO ·5H O concentration, NaCl concentration, H SO concentration and current density, were discussed in detail. The results indicated that copper recovery rate increased first with the increase of CuSO ·5H O NaCl, H SO and current density and then decreased with further increasing these conditions. NaCl, H SO and current density also showed a similar impact on copper purity, which also increased first and then decreased. Copper purity increased with the increase of CuSO ·5H O. When the concentration of CuSO ·5H O, NaCl and H SO was respectively 90, 40 and 118 g/L and current density was 80 mA/cm , copper recovery rate and purity was up to 97.32% and 99.86%, respectively. Thus, electrolysis proposes a feasible and prospective approach for waste printed circuit boards recycle, even for e-waste, though more researches are needed for industrial application.

关键词: Waste printed circuit boards (WPCBs)     Copper     Recovery rate     Purity     Electrolysis    

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1405-7

摘要:

• Copper fractal growth was observed during WPCBs recycling by slurry electrolysis.

关键词: Dendritic copper     Fractal growth     WPCBs     Slurry electrolysis    

Laser sintering of Cu nanoparticles on PET polymer substrate for printed electronics at different wavelengths

Juan Carlos HERNANDEZ-CASTANEDA, Boon Keng LOK, Hongyu ZHENG

《机械工程前沿(英文)》 2020年 第15卷 第2期   页码 303-318 doi: 10.1007/s11465-019-0562-x

摘要: This study explores the feasibility of different laser systems to sinter screen-printed lines from nonconductive copper nanoparticles (Cu NPs) on polyethylene terephthalate polymer film. These materials are commonly used in manufacturing functional printed electronics for large-area applications. Here, optical and thermal characterization of the materials is conducted to identify suitable laser sources and process conditions. Direct diode (808 nm), Nd:YAG (1064 nm and second harmonic of 532 nm), and ytterbium fiber (1070 nm) lasers are explored. Optimal parameters for sintering the Cu NPs are identified for each laser system, which targets low resistivity and high processing speed. Finally, the quality of the sintered tracks is quantified, and the laser sintering mechanisms observed under different wavelengths are analyzed. Practical considerations are discussed to improve the laser sintering process of Cu NPs.

关键词: laser sintering     copper nanoparticles     printed electronics    

Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced

《化学科学与工程前沿(英文)》 2023年 第17卷 第2期   页码 206-216 doi: 10.1007/s11705-022-2203-x

摘要: Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is an important organic electrode for solution-processed low-cost electronic devices. However, it requires doping and post-solvent treatment to improve its conductivity, and the chemicals used for such treatments may affect the device fabrication process. In this study, we developed a novel route for exploiting ultrafast lasers (femtosecond and picosecond laser) to simultaneously enhance the conductivity and transparency of PEDOT:PSS films and fabricate patterned solution-processed electrodes for electronic devices. The conductivity of the PEDOT:PSS film was improved by three orders of magnitude (from 3.1 to 1024 S·cm–1), and high transparency of up to 88.5% (average visible transmittance, AVT) was achieved. Raman and depth-profiling X-ray photoelectron spectroscopy revealed that the oxidation level of PEDOT was enhanced, thereby increasing the carrier concentration. The surface PSS content also decreased, which is beneficial to the carrier mobility, resulting in significantly enhanced electrical conductivity. Further, we fabricated semitransparent perovskite solar cells using the as-made PEDOT:PSS as the transparent top electrodes, and a power conversion efficiency of 7.39% was achieved with 22.63% AVT. Thus, the proposed route for synthesizing conductive and transparent electrodes is promising for vacuum and doping-free electronics.

关键词: PEDOT:PSS     ultrafast laser     transparent electrode     ST-PSCs     patterning    

标题 作者 时间 类型 操作

Rapid method for on-site determination of phenolic contaminants in water using a disposable biosensor

Yuanting LI, Dawei LI, Wei SONG, Meng LI, Jie ZOU, Yitao LONG

期刊论文

Defect passivation on cast-mono crystalline screen-printed cells

Alison WENHAM,Lihui SONG,Malcolm ABBOTT,Iskra ZAFIROVSKA,Sisi WANG,Brett HALLAM,Catherine CHAN,Allen BARNETT,Stuart WENHAM

期刊论文

Plated contacts for solar cells with superior adhesion strength to screen printed solar cells

R. CHEN,S. WANG,A. WENHAM,Z. SHI,T. YOUNG,J. JI,M. EDWARDS,A. SUGIANTO,L. MAI,S. WENHAM,C. CHONG

期刊论文

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

期刊论文

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

期刊论文

Cutting performance of surgical electrodes by constructing bionic microstriped structures

期刊论文

An investigation on patient dose in screen-film diagnostic radiology in Lhasa City, Xizang Autonomous

null

期刊论文

Hollow-fiber gas penetration electrodes efficiently produce renewable synthetic fuels

期刊论文

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

期刊论文

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

期刊论文

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

期刊论文

Copper recovery from waste printed circuit boards concentrated metal scraps by electrolysis

Xiaonan Liu, Qiuxia Tan, Yungui Li, Zhonghui Xu, Mengjun Chen

期刊论文

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

期刊论文

Laser sintering of Cu nanoparticles on PET polymer substrate for printed electronics at different wavelengths

Juan Carlos HERNANDEZ-CASTANEDA, Boon Keng LOK, Hongyu ZHENG

期刊论文

Ultrafast-laser-treated poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) electrodes with enhanced

期刊论文